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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 25, 1995 - Issue 12
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Original Articles

Application of the Intermolecular α-Amido-alkylation Reaction for the Synthesis of Tertiary Amides and 1-Substituted 2-Acyltetrahydroiso-Quinolines. Synthesis of (±)-Carnegine

Atanas P. Venkov Department of Chemistry, University of Plovdiv, Plovdiv, 4000, Bulgaria
&
Stela M. Statkova-Abeghe Department of Chemistry, University of Plovdiv, Plovdiv, 4000, Bulgaria
Pages 1817-1824 | Received 24 Sep 1994, Published online: 23 Sep 2006
 
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Abstract

Adducts 4 of Schiff bases and 3,4-dihydroisoquinolines with acyl chlorides react with Grignard reagents 5 in an intermolecular α-amidoalkylation reaction to the corresponding tertiary amides or 1-substituted 2-acyltetrahydroisoquinolines.

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