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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 26, 1996 - Issue 12
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Original Articles

A Facile Route to Convert Acetylacetone into Other β-Diketones with Acyl Chlorides Promoted by Samarium Triiodide

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Pages 2421-2427 | Received 23 Oct 1995, Published online: 23 Aug 2006
 

Abstract

Reaction of acetylacetone with acyl chlorides in the presence of SmI3 gave β-diketones RCOCH2COCH3 (I) or RCOCH2COR (II) in good yields under mild and neutral conditions.

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