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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 27, 1997 - Issue 2
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Original Articles

A Stereoselective Route to (E)-Vinylic Selenides through the Palladium-Catalyzed Cross-Coupling Reaction of Selenovinylicdialkylboranes with Alkyl Halides

Yu Yang Deartment of Chemistry, Hangzhou University, Hangzhou, 310028, China
&
Xian Huang Deartment of Chemistry, Hangzhou University, Hangzhou, 310028, China
Pages 345-349 | Received 16 Jul 1996, Published online: 22 Aug 2006
 
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Abstract

The reaction of selenoviylicdialkyboranes with alkyl halides takes place readily in the presence of Pd(PPh3)4 and sodium methoxide to afford (E)-vinylic selenides in excellent yields

Notes

Pd(PPh3)4 used for the hydroboration contiuned to be used as the Cross-Coupling reaction of C-C.

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