Abstract
Polyhedral oligomeric silsesquioxanes epoxy resin (GM-POSS) was prepared from 3-glycidyloxypropyl-trimethoxysilane (GTMS) and methyl triethoxysilane (MTES) by hydrolytic condensation. GM-POSS was characterized using liquid chromatography/mass spectrometry (LC/MS). The epoxy value of GM-POSS is 0.23 mol/100 g. The LC/MS analysis indicates that T 8 and T 9 cages are the majority and contain some amount of T 10. The co-cured nanocomposites of BPA epoxy resin with GM-POSS using 3-methyl-tetrahydrophthalic anhydride (MeTHPA) as the curing agent were prepared and the co-curing kinetics was investigated by nonisothermal differential scanning calorimetry (DSC). The relationship between apparent activation energy Ea and the conversion α was obtained by the isoconversional method of Kissinger, and E a is 68–78 k J/mol. The results show that these curing reactions can be described by the Šesták-Berggren (S-B) equation, which includes two parameters, m and n. For different mass ratio of GM-POSS and BPAER, the two reaction orders, m and n, are in the range of 0.25 ∼ 0.42 and 0.52 ∼ 1.28, respectively. The curing kinetics can be described by the equations
The authors gratefully acknowledge the financial support of the Nature Science Foundation (No. E2007000204) of Hebei Province, China.