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Abstract
New peroxo complexes of zirconium(IV) and uranium (IV) with dibasic acids and nitrogen containing heterocyclic bases have been prepared. The general compositions of the complexes are [M(O2)(DB)(L)2] and [M′O(O2)(DB)(L)2], where M, M′ are Zr (IV) or U (VI), DB = dianion of homophthalic acid or malonic acid and L = quinoline (Q) or isoquinoline (IQ). These complexes were characterized on the basis of elemental analyses, conductivity measurements, magnetic measurements, TLC, GLC, infrared spectral studies and by reactions with allyl alcohol, triphenylphosphine and triphenylarsine. The zirconium complexes were found to be octahedral, whereas the uranium complexes were seven-coordinated.
Referee I: D. L. Reger
Referee II: K. Moedritzer
Notes
Referee I: D. L. Reger
Referee II: K. Moedritzer