Synthesis and crystal structure of a new copper(II) binuclear complex bridged by the reduced derivative of a nitronyl nitroxide biradical

Abstract

A new copper(II) binuclear complex, [Cu(hfac)₂]₂(IMH)₂Ph(OMe)₂ ((IMH)₂Ph(OMe)₂ = 2,5-dimethoxyl-1,4-bis(4′,4′,5′,5′-tetramethylimidazoline-3′-oxide)benzene, hfac = hexafluoroacetonate), bridged by a reduced derivative of a nitronyl nitroxide biradical has been synthesized and characterized by X-ray crystallography. The complex crystallizes in the monoclinic space group P2₁/n, with a = 10.002(14), b = 19.950(3), c =  14.504(2) Å, β = 108.842(3)° and Z = 2. The structure refined to a final R value of 0.0644. The complex contains two copper(II) ions bridged by a reduced derivative of a nitronyl nitroxide biradical with a Cu ··· Cu separation of 8.430(2) Å.

Keywords:

• Biradical
• Copper(II) complex
• Crystal structure

Acknowledgments

This work was supported by the National Natural Science Foundation of China (Nos 20171025, 29961002 and 20331010) and the Natural Science Foundation of Yunnan Province (No. 1999B0003M).