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Journal of Coordination Chemistry Volume 57, 2004 - Issue 10
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Original Articles

Synthesis, crystal structure, spectroscopic and magnetic properties of [Cu(dien)2][Ni(CN)4]

Hui-Bo Zhou Department of Chemistry, Nankai University, Tianjin 300071, P.R. China
,
Mao Liang Department of Chemistry, Nankai University, Tianjin 300071, P.R. China
,
Li-Na Zhu Department of Chemistry, Nankai University, Tianjin 300071, P.R. China
,
Wen Dong Department of Chemistry, Nankai University, Tianjin 300071, P.R. China
,
Dai-Zheng Liao Department of Chemistry, Nankai University, Tianjin 300071, P.R. China; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Science, Fuzhou Fujian 350002, P.R. ChinaCorrespondence[email protected]
,
Zong-Hui Jiang Department of Chemistry, Nankai University, Tianjin 300071, P.R. China; State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, P.R. China
,
Shi-Ping Yan Department of Chemistry, Nankai University, Tianjin 300071, P.R. China; Earth Materials Chemistry and Application, Peking University, Beijing 100871, P.R. China
&
Peng Cheng Department of Chemistry, Nankai University, Tianjin 300071, P.R. China
 show all
Pages 865-870 | Received 13 Jan 2004, Published online: 25 Jan 2007
 
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Abstract

A new complex, [Cu(dien)2][Ni(CN)4] (1) [dien = diethylenetriamine] has been obtained by the reaction of Cu(ClO4)2·6H2O, diethylenetriamine and K2[Ni(CN)4] in water, and has been characterized spectroscopically. The crystal structure of 1 has been determined. In the complex, two tridentate dien ligands are bonded to the copper(II) ion in a distorted octahedral arrangement and the

anion remains outside the coordination sphere.

Acknowledgements

This work was supported by the National Natural Science Foundation of China (Nos 50172021, 90101028, 20331010).

Supplementary Material

Crystallographic data for the structural analysis have been deposited with the Cambridge Crystallographic Data Centra, CCDC No 228067. Copies of this information can be obtained free of charge from The Director, CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (Fax: +44-1223-336-033; E-mail: [email protected] or www: http://www.ccdc.cam.ac.uk).

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