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Journal of Coordination Chemistry Volume 57, 2004 - Issue 10
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Original Articles

Synthesis of a re(VI)-catecholato complex by air oxidation of oxorhenium(V)

T.I.A. Gerber Department of Chemistry, University of Port Elizabeth, PO Box 1600, Port Elizabeth 6000, South AfricaCorrespondence[email protected]
,
D. Luzipo Department of Chemistry, University of Port Elizabeth, PO Box 1600, Port Elizabeth 6000, South Africa
&
P. Mayer Department of Chemistry, Ludwig-Maximilians University, D-81377, München, Germany
Pages 893-897 | Received 02 Mar 2004, Published online: 25 Jan 2007
 
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Abstract

The complex [Re(ddcat)3] (H2ddcat = 3,5-di-tert-butylcatechol) was prepared by the reaction of either cis-[ReVO2I(PPh3)2] or (n-Bu4N)[ReVOCl4] with H2ddcat in toluene in air. X-ray structure determination of the product unequivocally illustrates that the bidentate chelates are in the catecholato rather than the semiquinone form and that the metal has a formal oxidation state of +VI.

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