Synthesis, characterization and biological activities of mononuclear and binuclear Fe(III) complexes with some symmetric and unsymmetric Schiff-base ligands

Abstract

A series of mononuclear and binuclear Fe(III) complexes of some new symmetrical and unsymmetrical Schiff bases containing quinoline derivatives were synthesized and characterized by elemental and thermal analysis, conductance measurements and IR spectra. In mononuclear complexes, the unsymmetric Schiff bases are monobasic tetradentate towards the Fe(III) ion. However, in binuclear complexes, the symmetric Schiff-base ligands behave as monobasic bidentate towards each Fe(III) ion. The structure of the solid complexes are discussed and based on magnetic susceptibility measurements, electronic and ESR spectral studies. The biological activities of the ligands and their complexes are reported.

Keywords:

• Iron(III)
• Schiff-base
• Macrocycle
• Biological activity
• Binuclear