Abstract
New alkaline-earth metal cryptates [ML](ClO4)2 · solvent (M = Ca2+, Sr2+, Ba2+; L = 1,4, 12,15,18,26,31,39,42,43,44-undecaazapentacyclo-[13.13.13.16,10.120,24.133,37]-tetratetraconta-4, 6, 8, 10(44), 11,18,20,22,24(43),25,31,33,35,37(42),38-pentadecaene) were synthesized by [2 + 3] template condensation of tris(2-aminoethyl)amine with 2,6-diformylpyridine and characterized by physical methods. The crystal structure of the calcium cryptate was determined. The central atom is nine coordinate with three pyridyl and six imino nitrogen atoms. The coordination polyhedron can be described as slightly distorted tricapped trigonal prism.
Acknowledgements
The work was supported by the National Natural Science Foundation of China for the grant No. 20671075, the Education Office of Hubei Province, PR China for the research grant No. D200515004 and the Natural Science Foundation of Hubei Province, PR China for the research grant No. 2005ABA021.