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Journal of Coordination Chemistry Volume 61, 2008 - Issue 5
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Original Articles

Synthesis, crystal structure and saturable absorption in the near-IR regions of a new copper complex of dmit: hexadecyltrimethylammonium bis(2-thioxo-1,3-dithiole-4,5-dithiolato)-copper

Yan-Ling Wang School of Petroleum Engineering, China University of Petroleum (East China), Dongying, 257061, People's Republic of ChinaCorrespondence[email protected]
,
Dong Xu State Key Laboratory of Crystal Materials and Institute of Crystal Materials, Shandong University, Jinan, 250100, People's Republic of China
,
Wen-Tao Yu State Key Laboratory of Crystal Materials and Institute of Crystal Materials, Shandong University, Jinan, 250100, People's Republic of China
,
Xiang-Bing Sun Department of Optics, School of Information Science and Engineering, Shandong University, Jinan, 250100, People's Republic of China
,
Quan Ren Department of Optics, School of Information Science and Engineering, Shandong University, Jinan, 250100, People's Republic of China
,
Guang-hui Zhang State Key Laboratory of Crystal Materials and Institute of Crystal Materials, Shandong University, Jinan, 250100, People's Republic of China
,
Yun-Qiao Ding School of Chemistry and Chemical Engineering, Shandong University, Jinan, 250100, People's Republic of China
,
Xin-qiang Wang State Key Laboratory of Crystal Materials and Institute of Crystal Materials, Shandong University, Jinan, 250100, People's Republic of China
,
Wen-feng Guo State Key Laboratory of Crystal Materials and Institute of Crystal Materials, Shandong University, Jinan, 250100, People's Republic of China
,
Hong-Yu Chen State Key Laboratory of Crystal Materials and Institute of Crystal Materials, Shandong University, Jinan, 250100, People's Republic of China
&
Lin Feng Department of Optics, School of Information Science and Engineering, Shandong University, Jinan, 250100, People's Republic of China
 show all
Pages 768-775 | Received 20 Nov 2005, Accepted 24 Mar 2006, Published online: 03 Mar 2008
 
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Abstract

A new copper complex of dmit, hexadecyltrimethylammonium bis(2-thioxo-1,3-dithiole-4,5-dithiolato)-copper([C16H33(CH3)3N][Cu(dmit)2], abbreviated as CTCU, C16H33(CH3)3N = hexadecyltrimethylammonium, dmit = 2-thioxo-1,3-dithiole-4,5-dithiolate) has been synthesized and its structure determined by X-ray diffraction. The saturable absorption of CTCU at 1053 nm shows promise as a Q-switch dye in the near IR regions.

Acknowledgements

This work is supported by a grant from the High Technology Development Project of China (No. 2002AA313070) and the Natural Science Foundation of China (Nos 60476020, 60377016 and 50272037).

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