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Journal of Coordination Chemistry Volume 61, 2008 - Issue 8
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Original Articles

Hydrothermal syntheses and crystal structures of hybrid materials based on Keggin cluster modified by iron complexes

Jingquan Sha Faculty of Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Northeast Normal University, Changchun, Jilin 130024, P.R. China; Faculty of Chemistry and Pharmacy, Jiamusi University, Jiamusi, Heilong, Jiang 154007, P.R. China
,
Jun Peng Faculty of Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Northeast Normal University, Changchun, Jilin 130024, P.R. ChinaCorrespondence[email protected]
,
Hongsheng Liu Faculty of Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Northeast Normal University, Changchun, Jilin 130024, P.R. China
,
Jing Chen Faculty of Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Northeast Normal University, Changchun, Jilin 130024, P.R. China
,
Aixiang Tian Faculty of Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Northeast Normal University, Changchun, Jilin 130024, P.R. China
,
Baoxia Dong Faculty of Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Northeast Normal University, Changchun, Jilin 130024, P.R. China
&
Pengpeng Zhang Faculty of Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Northeast Normal University, Changchun, Jilin 130024, P.R. China
 show all
Pages 1221-1233 | Received 29 Jun 2007, Accepted 04 Jul 2007, Published online: 24 Apr 2008
 
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Abstract

Three new organic-inorganic hybrid complexes based on the Keggin polyoxometalates (POMs) modified by transition metal iron and N-ligand organic moiety: [Fe(phen)3]2 (1) [Fe(phen)2(H2O)]2  · 2H2O (2) and [Fe(phen)3]2  · 0.5H2O (3) (phen = 1,10-phenanthroline) have been hydrothermally synthesized and structurally characterized. Crystal data for complex 1: C72H48Fe2M12N12O41PV, triclinic, , a = 11.6618(2) Å, b = 13.8523(2) Å, c = 14.9168(2) Å, α = 105.87(3)°, β = 93.103(2)°, γ = 96.609(2)°, V = 2293.2(5) Å3, Z = 1; for complex 2: C48H32Fe2PMo12N8O44, triclinic, , b = 13.357(3) Å, c = 13.701(3) Å, α = 69.09(3)°, β = 71.37(3)°, γ = 78.21(3)°, V = 1766.4(6) Å3, Z = 1; for complex 3: C72H50Fe2Mo12N12O41Ge, triclinic, , b = 13.676(3) Å, c = 14.627(3) Å, α = 105.05(3)°, β = 109.64(3)°, γ = 93.07(3) °, V = 2185.6(7) Å3, Z = 1. Other characterizations by element analysis, IR, XPS and TGA analysis are also described. Their electrochemical properties have been studied in the paper.

Acknowledgements

The authors acknowledge financial support from the National Science Foundation of China (20671016).

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