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Journal of Coordination Chemistry Volume 61, 2008 - Issue 18
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Original Articles

Syntheses and structures of three new coordination polymers with the flexible 1,4-bis(imidazol-1-yl)butane ligand

Kui Liu College of Chemistry and Chemical Engineering, Suzhou University, Key Laboratory of Organic Synthesis of Jiangsu Province, Suzhou 215123, P.R. China
,
Yu-Mei Zhang College of Chemistry and Chemical Engineering, Suzhou University, Key Laboratory of Organic Synthesis of Jiangsu Province, Suzhou 215123, P.R. China
,
Yuan Yang College of Chemistry and Chemical Engineering, Suzhou University, Key Laboratory of Organic Synthesis of Jiangsu Province, Suzhou 215123, P.R. China
,
Bao-Long Li College of Chemistry and Chemical Engineering, Suzhou University, Key Laboratory of Organic Synthesis of Jiangsu Province, Suzhou 215123, P.R. China; State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, P.R. ChinaCorrespondence[email protected]
&
Yong Zhang College of Chemistry and Chemical Engineering, Suzhou University, Key Laboratory of Organic Synthesis of Jiangsu Province, Suzhou 215123, P.R. China
Pages 2926-2934 | Received 18 Oct 2007, Accepted 03 Dec 2007, Published online: 22 Sep 2010
 
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Abstract

Three new coordination polymers [Co(bimb)2(NCS)2] n (1), {[Co(bimb)2(dca)2] · CH3CN} n (2) and [Cu(bimb)2(NO3)2] n (3) (bimb = 1,4-bis(imidazol-1-yl)butane, dca = dicyanamide) were synthesized and characterized. In 1, each Co(II) links two Co(II)'s by double bimb ligands and extends to form a one-dimensional chain containing the Co2(bimb)2 22-membered metallocycle. 2 and 3 are two-dimensional (4, 4) networks linked by bimb bridges. The conformations of the bimb ligands in 1, 2 and 3 are analyzed.

Acknowledgements

This work was supported by the Natural Science Foundation of China (No. 20671066), the Jiangsu Province (No. BK2006049) and the Funds of State Key Laboratory of Coordination Chemistry.

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