Spectroscopic, magnetic and thermal studies on complexes of Cu(II) and VO²⁺ with diacetylmonoxime derivatives: new method for extraction of Cu(II)

Abstract

The coordination behavior of Cu(II) and VO²⁺ towards some oximes has been investigated. The isolated complexes were characterized by elemental analysis, molar conductance, magnetic moment, spectra (electronic, IR, ESR and mass) and thermal measurements. The IR spectra showed most ligands are deprotonated during complex formation acting as mononegative bi- or tridentate, binegative tetradentate and neutral tridentate. The magnetic moments and electronic spectra showed octahedral, square pyramidal and square-planar structures for the Cu(II) and VO²⁺ complexes. The ESR spectra of the complexes are quite similar and exhibit axial symmetric g-tensor parameters with g _∥ > g _⊥ > 2.0023 and confirmed the structures. The TG curves showed decomposition steps and indicate stability of the complexes. The ligands can remove Cu(II) ions from water by flotation technology using oleic acid surfactant with high efficiency.

Keywords:

• Complexes
• Thiosemicarbazone
• Spectra
• Thermal analysis
• Flotation