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Journal of Coordination Chemistry Volume 63, 2010 - Issue 3
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Original Articles

Hydrothermal syntheses and characterizations of two compounds assembled from tungstates and bpy (bpy = 4,4′-bipyridine)

Yan Wang Department of Chemistry, College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, China
,
Ling Ye State Key Laboratory of Supramolecular Structure and Materials, Jilin University, Changchun 130023, China
,
Hong Ding Department of Chemistry, College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, China
,
Tie-Gang Wang Department of Chemistry, College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, China
,
Guo-Wu Wang Department of Chemistry, College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, China
,
Shu-Yun Shi Department of Chemistry, College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, China
,
Xiao-Bing Cui Department of Chemistry, College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, ChinaCorrespondence[email protected]
&
Ji-Qing Xu Department of Chemistry, College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, ChinaCorrespondence[email protected]
 show all
Pages 426-434 | Received 04 Jun 2009, Accepted 02 Sep 2009, Published online: 04 Jan 2010
 
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Abstract

Two compounds based on polyoxometalates, (4,4′-H2bpy)7(4,4′-Hbpy)[]2[] ·10H2O (1) and (4,4′-H2bpy)6(4,4′-bpy)[]2 · 18H2O (2), have been prepared under hydrothermal conditions and characterized by IR, XPS spectra, TG analyses, and single crystal X-ray diffraction. Both compounds consist of 4,4′-bipyridine units and polyoxometalates: []5− for 1 and []6− for 2. In addition, 1 contains both Keggin-type and disordered Keggin-type anions, while 2 contains a (H2O)10 water cluster.

Acknowledgments

This work was financially supported by the National Natural Science Foundation of China (No. 20571032 and No. 20333070).

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