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Journal of Coordination Chemistry Volume 63, 2010 - Issue 5
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Original Articles

Syntheses, crystal structures, and thermal stabilities of the first Hofmann-DMF-type complexes Zn(DMF)2M(CN)4 (M = Ni, Pd, Pt)

Runqin Lu School of Material Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, P.R. China
,
Hu Zhou School of Material Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, P.R. China
,
Yingying Chen School of Material Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, P.R. China
,
Jie Xiao School of Material Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, P.R. China
&
Aihua Yuan School of Material Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, P.R. ChinaCorrespondence[email protected]
Pages 794-800 | Received 04 Jul 2009, Accepted 23 Oct 2009, Published online: 08 Mar 2010
 
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Abstract

The first Hofmann-DMF-type complexes Zn(DMF)2M(CN)4 (M = Ni (1), Pd (2), Pt (3)) have been synthesized by solution diffusion and characterized structurally by single-crystal X-ray diffraction. The structure consists of 2-D corrugated sheets stacking along the a-axis in an ABAB packing mode without interpenetration. The octahedral Zn ions and square-planar M ions occupy special positions of 2/m site symmetry. The DMF, except for six methyl H atoms, lies on a crystallographic mirror plane; the DMF molecules coordinate to axial sites of Zn on both sides of the sheet. The framework of 1 begins to collapse with loss of coordinated DMF.

Acknowledgment

This work is supported by the University Natural Science Foundation of Jiangsu Province (No. 07KJB150030).

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