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Journal of Coordination Chemistry Volume 63, 2010 - Issue 10
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Original Articles

Ruthenium(III) tetradentate Schiff-base complexes: spectral, catalytic, and its biocidal efficacy

S. Arunachalam Post Graduate and Research Department of Chemistry, Sri Ramakrishna Mission Vidyalaya College of Arts and Science, Coimbatore–641020, Tamil Nadu, India
,
N. Padma Priya Post Graduate and Research Department of Chemistry, Sri Ramakrishna Mission Vidyalaya College of Arts and Science, Coimbatore–641020, Tamil Nadu, India
,
C. Saravanakumar Post Graduate and Research Department of Chemistry, Sri Ramakrishna Mission Vidyalaya College of Arts and Science, Coimbatore–641020, Tamil Nadu, India
,
C. Jayabalakrishnan Post Graduate and Research Department of Chemistry, Sri Ramakrishna Mission Vidyalaya College of Arts and Science, Coimbatore–641020, Tamil Nadu, India
&
V. Chinnusamy Post Graduate and Research Department of Chemistry, Sri Ramakrishna Mission Vidyalaya College of Arts and Science, Coimbatore–641020, Tamil Nadu, IndiaCorrespondence[email protected]
Pages 1795-1806 | Received 10 Aug 2009, Accepted 03 Feb 2010, Published online: 11 Jun 2010
 
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Abstract

New six-coordinate ruthenium(III) Schiff-base complexes of general formula [Ru(X)(PPh3)(L)] (where X = Cl/Br and L = mononucleating bibasic tetradentate ligand derived by condensing actetoacetanilide/acetoacetotoludide with o-aminophenol/o-aminothiophenol/o-aminobenzoic acid in 1 : 2 molar ratio in ethanol) have been synthesized and characterized by physico-chemical and spectroscopic methods. The new ruthenium(III) complexes possess 2NO/2NS metal binding sites and are catalysts for the oxidation of alcohols using molecular oxygen as co-oxidant and in C–C coupling reactions. These complexes possess good biocidal (antibacterial and antifungal) activity.

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