Abstract
Bromido complex of platinum(IV) with (S,S)-ethylenediamine-N,N′-di-2-(3-cyclohexyl)propanoic acid was synthesized. The reaction was performed in water solution in the presence of lithium hydroxide. In this reaction system, (S,S)-ethylenediamine-N,N′-di-2-(3-cyclohexyl)propanoic acid exists as the dicarboxylato anion and coordinates as a tetradentate ONNO ligand. The complex was characterized by 1H and 13C NMR, IR and UV-Vis spectroscopy. The sym-cis configuration has been elucidated using DFT calculations.
Acknowledgment
This work was supported by the Ministry of Science of the Republic of Serbia, Grant No. 142010.