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Journal of Coordination Chemistry Volume 64, 2011 - Issue 7
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Original Articles

Hydrothermal synthesis, characterization, and luminescence of two new arsenic–vanadium compounds with a γ-[As8V14O42(H2O)]4− anion

Congling Wang State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, P. R. China
,
Guangpeng Zhou Department of Applied Chemistry, Harbin Institute of Technology, Harbin 150001, P. R. China
,
Zhibin Zhang State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, P. R. China
,
Dunru Zhu State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, P. R. China
&
Yan Xu State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, P. R. ChinaCorrespondence[email protected]
Pages 1198-1206 | Received 29 Nov 2010, Accepted 24 Jan 2011, Published online: 04 Apr 2011
 
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Abstract

Two new compounds, [Zn(phen)3]2[γ-As8V14O42(H2O)] · 4H2O (1) and [Cd(phen)3]2[γ-As8V14O42(H2O)] · 2H2O (2) (phen = 1,10′-phenanthroline), have been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction, infrared spectrum, and thermogravimetric analysis. Compound 1 crystallizes in the triclinic space group P 1 with a = 11.429(4) Å, b = 15.760(5) Å, c = 15.952(5) Å, α = 108.825(5)°, β = 92.194(5)°, γ = 104.155(5)°, V = 2615.6(15) Å3, Z = 1; 2 crystallizes in the triclinic space group P 1 with a = 11.450(4) Å, b = 15.629(6) Å, c = 16.302(6) Å, α = 109.177(5)°, β = 92.628(5)°, γ = 104.251(4)°, V = 2644.8(17) Å3, Z = 1. Single-crystal structural analysis shows that both 1 and 2 consist of a new type of [γ-As8V14O42(H2O)]4− cluster anion.

Acknowledgment

We thank the National Natural Science Foundation of China (20971068) for financial support.

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