Synthesis, crystal structures, and properties of two heterometallic Cu(II)–M(II) (M = Zn, Ni) oxamidato-bridged coordination complexes

Abstract

Two heterometallic coordination complexes, {[Cu(aeop)Zn(H₂O)₃]₂ · 3H₂O} _n (1) and [Cu(aeop)Ni(H₂O)₄] · 4H₂O (2) (H₄aeop = N-(2-aminoterephthalic acid)-N′-(1,3-propanediamine)oxamidate), have been synthesized and characterized by elemental analyses, IR, UV spectroscopy, thermogravimetric analysis, and X-ray crystal diffraction. Complex 1 features a 1-D chain constructed from neutral tetranuclear units. Complex 2 is a neutral binuclear complex. Through intermolecular hydrogen-bonding interactions, 2 gives a 3-D network structure. The variable temperature magnetic susceptibility measurements (2–300 K) of 2 show a pronounced antiferromagnetic interaction between the copper(II) and nickel(II), and the exchange integral J is equal to −42.7 cm⁻¹.

Keywords:

• Heterobimetallic complexes
• Oxamidate-bridge
• Crystal structure
• Magnetic properties

Acknowledgments

We acknowledge the generous financial support of the Natural Science Foundation of Henan Province (no. 092300410031).