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Original Articles

Cadmium(II) nano-dimensional square grid polymers based on bis(imidazol-1-yl-methyl)benzene: synthesis, characterization, and photoluminescence

, , , , &
Pages 3605-3613 | Received 07 Feb 2012, Accepted 12 Jun 2012, Published online: 06 Sep 2012
 

Abstract

Two new nano-dimensional square grid metal–organic polymers, {[Cd(1,3-bix)2(H2O)2](NO3)2} n (1) and [Cd(1,3-bix)2(NO3)2] n (2) (1,3–bix = 1,3-bis(imidazol-1-yl-methyl)benzene), have been synthesized and structurally characterized by single-crystal X-ray crystallography and FT-IR spectroscopy. Polymers 1 and 2 are 2-D layer structures consisting of nano-dimensional square grid units. The photoluminescent properties of 1 and 2 were investigated.

Acknowledgments

This work was supported by the National Natural Science Foundation of China (grant no. 21171133), Zhejiang Provincial Natural Science Foundation (no. X063638), and by Tarbiat Modares University.

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