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Journal of Coordination Chemistry Volume 66, 2013 - Issue 9
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Articles

Three lanthanide-based coordination compounds with 5-[N-acetato(4-pyridyl)]tetrazolate

Ming-Hua He Jiangsu Laboratory of Advanced Functional Materials, Department of Chemistry and Materials Engineering, Changshu Institute of Technology, Changshu, P.R. China
,
Cheng Ji Jiangsu Laboratory of Advanced Functional Materials, Department of Chemistry and Materials Engineering, Changshu Institute of Technology, Changshu, P.R. China
,
Zhen-Dong Shen Jiangsu Laboratory of Advanced Functional Materials, Department of Chemistry and Materials Engineering, Changshu Institute of Technology, Changshu, P.R. China
,
Qiao-Yun Li Jiangsu Laboratory of Advanced Functional Materials, Department of Chemistry and Materials Engineering, Changshu Institute of Technology, Changshu, P.R. ChinaCorrespondence[email protected]
,
Gao-Wen Yang Jiangsu Laboratory of Advanced Functional Materials, Department of Chemistry and Materials Engineering, Changshu Institute of Technology, Changshu, P.R. China
,
Wei Shen Jiangsu Laboratory of Advanced Functional Materials, Department of Chemistry and Materials Engineering, Changshu Institute of Technology, Changshu, P.R. China
,
Qing-Guo Qiou Jiangsu Laboratory of Advanced Functional Materials, Department of Chemistry and Materials Engineering, Changshu Institute of Technology, Changshu, P.R. China
&
Xiao-Feng Shen Jiangsu Laboratory of Advanced Functional Materials, Department of Chemistry and Materials Engineering, Changshu Institute of Technology, Changshu, P.R. China
 show all
Pages 1538-1548 | Received 23 Jul 2012, Accepted 06 Dec 2012, Published online: 19 Apr 2013
 
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Abstract

Reaction of 5-[N-acetato(4-pyridyl)]tetrazolate (a4-ptz) potassium salt with lanthanide(III) chlorides, produced three new coordination compounds, [Ln(a4-ptz)2(H2O)4]·Cl·2H2O (Ln = La(1), Eu(2) and Tb(3)). These compounds were characterized by elemental analysis, IR spectroscopy, and single-crystal X-ray diffraction. Complexes 1–3 displayed 1-D structures. Luminescences of 1–3 were investigated at room temperature in the solid state.

Acknowledgment

The authors wish to thank the Key Laboratory of Advanced Functional Materials of Jiangsu Province of China for financial support.

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