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Articles

Solvent-dependent conformational polymorphism in the crystal structure of mercuric bromide adduct of 1,1′-bis(diphenylphosphino)ferrocene

, &
Pages 2290-2296 | Received 28 Oct 2012, Accepted 08 Mar 2013, Published online: 11 Jun 2013
 

Abstract

Two polymorphs of dinuclear mercury–iron complexes, [HgBr2(dppf)] (1) where dppf is 1,1′-bis(diphenylphosphino)ferrocene, are prepared and crystal structures are determined by X-ray crystallography. The reaction of mercury(II) bromide with dppf in methanol–dichloromethane led to orange block polymorph. After crystallization of this complex in DMSO, a red needle polymorph was obtained.

Acknowledgment

We are grateful to the University of Tehran for financial support.

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