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Journal of Coordination Chemistry Volume 66, 2013 - Issue 20
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Original Articles

Synthesis, crystal structure, and properties of three supramolecular compounds based on Keggin-type phosphomolybdate and different flexible ligands

Mingli QiKey Laboratory for Photonic and Electronic Bandgap Materials, Ministry of Education, Harbin Normal University, Harbin, P.R. China;Key Laboratory of Synthesis of Functional Materials and Green Catalysis, College of Heilongjiang Province, Harbin Normal University, Harbin, P.R. China
,
Kai YuKey Laboratory for Photonic and Electronic Bandgap Materials, Ministry of Education, Harbin Normal University, Harbin, P.R. China;Key Laboratory of Synthesis of Functional Materials and Green Catalysis, College of Heilongjiang Province, Harbin Normal University, Harbin, P.R. China
,
Zhanhua SuKey Laboratory for Photonic and Electronic Bandgap Materials, Ministry of Education, Harbin Normal University, Harbin, P.R. China;Key Laboratory of Synthesis of Functional Materials and Green Catalysis, College of Heilongjiang Province, Harbin Normal University, Harbin, P.R. China
,
Chunxiao WangKey Laboratory for Photonic and Electronic Bandgap Materials, Ministry of Education, Harbin Normal University, Harbin, P.R. China;Key Laboratory of Synthesis of Functional Materials and Green Catalysis, College of Heilongjiang Province, Harbin Normal University, Harbin, P.R. China
,
Chunmei WangKey Laboratory for Photonic and Electronic Bandgap Materials, Ministry of Education, Harbin Normal University, Harbin, P.R. China;Key Laboratory of Synthesis of Functional Materials and Green Catalysis, College of Heilongjiang Province, Harbin Normal University, Harbin, P.R. China
,
Baibin ZhouKey Laboratory for Photonic and Electronic Bandgap Materials, Ministry of Education, Harbin Normal University, Harbin, P.R. China;Key Laboratory of Synthesis of Functional Materials and Green Catalysis, College of Heilongjiang Province, Harbin Normal University, Harbin, P.R. ChinaCorrespondence[email protected]
&
Chuncheng ZhuKey Laboratory for Photonic and Electronic Bandgap Materials, Ministry of Education, Harbin Normal University, Harbin, P.R. China;Key Laboratory of Synthesis of Functional Materials and Green Catalysis, College of Heilongjiang Province, Harbin Normal University, Harbin, P.R. China
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Pages 3531-3543 | Received 05 Jul 2013, Accepted 21 Aug 2013, Published online: 06 Nov 2013
 
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Abstract

Three supramolecular compounds based on Keggin phosphomolybdate and different flexible ligands, Cu3(bei)6(PMo12O40)2·6H2O (1), (H2bbi)(Hbbi)(PMo12O40)·2H2O (2), and (H2bpp)3(PMo12O40)2·6H2O (3) (bei = 1,1’-(1,2-ethanediyl)bis(imidazole), bbi = 1,1’-(1,4-butanediyl)bis(imidazole), bpp = 1,3-bi(4-pyridyl)propane)), have been hydrothermally prepared and characterized by elemental analysis, IR, TG, XRD, and single-crystal X-ray diffraction. Crystal data analysis reveals that 1–3 are composed of discrete [Cu(bei)2]2+ complex cations, protonated bbi and bpp cations, respectively, with [PMo12O40]3-. All three compounds exhibit interesting supramolecular frameworks via electrostatic interactions and hydrogen bonds. Their electrochemistry, electrocatalytic behavior, and solid state fluorescence at room temperature have been investigated.

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