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Journal of Coordination Chemistry Volume 67, 2014 - Issue 9
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Original Articles

Three polynuclear complexes with bridging triazole ligand: crystal structures

Lei ShenJiangsu Key Laboratory of Advanced Functional Materials, Department of Chemistry & Materials Engineering, Changshu Institute of Technology, Changshu, PR China
,
Qiu-Jie XiaJiangsu Key Laboratory of Advanced Functional Materials, Department of Chemistry & Materials Engineering, Changshu Institute of Technology, Changshu, PR China
,
Lei WangState Key Laboratory of Materials-oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing Tech University, Nanjing, PR China
,
Jie YangJiangsu Key Laboratory of Advanced Functional Materials, Department of Chemistry & Materials Engineering, Changshu Institute of Technology, Changshu, PR China
,
Yong ChenJiangsu Key Laboratory of Advanced Functional Materials, Department of Chemistry & Materials Engineering, Changshu Institute of Technology, Changshu, PR China
,
Xiao-Yan TangJiangsu Key Laboratory of Advanced Functional Materials, Department of Chemistry & Materials Engineering, Changshu Institute of Technology, Changshu, PR China
,
Yun-Sheng MaJiangsu Key Laboratory of Advanced Functional Materials, Department of Chemistry & Materials Engineering, Changshu Institute of Technology, Changshu, PR China
,
Rong-Xin YuanJiangsu Key Laboratory of Advanced Functional Materials, Department of Chemistry & Materials Engineering, Changshu Institute of Technology, Changshu, PR ChinaCorrespondence[email protected]
&
Dun-Ru ZhuState Key Laboratory of Materials-oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing Tech University, Nanjing, PR ChinaCorrespondence[email protected]
 show all
Pages 1573-1583 | Received 12 Jun 2012, Accepted 25 Mar 2014, Published online: 20 Jun 2014
 
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Abstract

Three polynuclear clusters, [Cu4L8](ClO4)4·4H2O (1), [Zn3L6(H2O)6](ClO4)6·6H2O (2), and [Mn3L6(CH3OH)6](ClO4)6·4.5H2O (3) (L = 4-(4-hydroxyphenyl)-1,2,4-triazole), obtained by the reactions of M(ClO4)2·6H2O with L have been isolated and structurally characterized. Complex 1 featured a tetranuclear Cu(I) structure. Both 2 and 3 are linear hexapositive trimers linked by three N1,N2–1,2,4-triazole ligands to the divalent central and terminal metal ions. Furthermore, the luminescence properties of 2 were investigated at room temperature in the solid state.

Graphical Abstract

Three new complexes with 4-(4-hydroxyphenyl)-1,2,4-triazole (L), [Cu4L8](ClO4)4·4H2O (1), [Zn3L6(H2O)6](ClO4)6·6H2O (2) and [Mn3L6(CH3OH)6](ClO4)6·4.5H2O (3), have been synthesized and characterized by single crystal X-ray crystallography.

Funding

This work was supported by the Natural Science Fund of Jiangsu Province of PR China [grant number BK2012643], [grant number 12KJA150001], NSFC [grant number 21001018], [grant number 21171093], [grant number 21201025] and the start-up grant from CSLG [grant number KYZ2010131Z].

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