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Journal of Coordination Chemistry Volume 68, 2015 - Issue 6
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Original Articles

POM-assisted synthesis of the first cyclohexanediamine-based Salen-type MnIII-dimer complexes

Qiong WuDepartment of Chemical Science and Technology, Kunming University, Kunming, PR China;Center for Disease Control and Prevention, Chengdu Military Region, Kunming, PR ChinaCorrespondence[email protected]
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Qing PuDepartment of Chemical Science and Technology, Kunming University, Kunming, PR ChinaView further author information
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Yongmei WuSchool of International Cultures and Education, Yunnan University of Finance and Economics, Kunming, PR ChinaView further author information
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Hongjuan ShiDepartment of Chemical Science and Technology, Kunming University, Kunming, PR ChinaView further author information
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Yanfang HeDepartment of Chemical Science and Technology, Kunming University, Kunming, PR ChinaView further author information
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Jun LiMedical School, Kunming University, Kunming, PR ChinaView further author information
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Quanshui FanCenter for Disease Control and Prevention, Chengdu Military Region, Kunming, PR ChinaCorrespondence[email protected]
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Pages 1010-1020 | Received 27 Aug 2014, Accepted 30 Dec 2014, Published online: 27 Feb 2015
 
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Abstract

The reaction between manganese nitrate and N,Nʹ-(±)-ethylene-bis(salicylicyclohexanediaminate) ((±)-salcy) in dilute lacunary polyoxoanion [PW9O34]9− solution led to isolation of a new Mn-dimer, [Mn((±)-salcy)(N3)]2 (1). Structural analysis indicates that 1 represents the first salcy-based Mn-dimer complex. Magnetic susceptibility studies reveal that 1 shows single-molecule magnet (SMM) behavior from 2 to 5 K.

Additional information

Funding

This work was supported by the National Natural Science Foundation of China [grant number 21201090], the Science and Technology Department of Yunnan Province Youth Project [grant number 2012FD045], and Kunming University Talent Introduction Funds [grant number YJL11028].

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