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Journal of Coordination Chemistry Volume 68, 2015 - Issue 8
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Original Articles

Syntheses, crystal structures, and some spectroscopic properties of zinc(II) complexes with N2O2 ligands derived from m-phenylenediamine and m-aminobenzylamine

Yasunori YamadaDepartment of Chemistry and Applied Chemistry, Graduate School of Science and Engineering, Saga University, Saga, JapanCorrespondence[email protected]
,
Takeshi ImariDepartment of Chemistry and Applied Chemistry, Graduate School of Science and Engineering, Saga University, Saga, Japan
&
Daishin KooriDepartment of Chemistry and Applied Chemistry, Graduate School of Science and Engineering, Saga University, Saga, Japan
Pages 1433-1440 | Received 21 Nov 2014, Accepted 29 Jan 2015, Published online: 09 Mar 2015
 
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Abstract

The reaction of bis(salicylidene)-m-phenylenediamine with zinc(II) ion affords a 2 : 2 dinuclear zinc(II) complex formulated as [Zn2(L1)2]. A similar 2 : 2 dinuclear zinc(II) complex, [Zn2(L2)2], can be obtained by reaction of bis(salicylidene)-m-aminobenzylamine with zinc(II) ion. These two dinuclear complexes slightly differ in their crystal structures, especially coordination environments around the zinc(II) centers, depending on the dissimilar flexibilities of the two ligands. The differences between the two complexes are reflected in their diffuse reflectance and photoluminescence behaviors.

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