Advanced search
Publication Cover
Journal of Coordination Chemistry Volume 68, 2015 - Issue 9
Submit an article Journal homepage
121
Views
2
CrossRef citations to date
0
Altmetric
Articles

Assembly of 1-D and decanuclear cage compounds from copper halide, cyclohexenephosphonic acid, and 3-(2-pyridyl)pyrazole

Yun-sheng MaSchool of Chemistry and Materials Engineering, Jiangsu Key Laboratory of Advanced Functional Materials, Changshu Insititute of Technology, Changshu, PR ChinaCorrespondence[email protected]
View further author information
,
Zhen YangSchool of Chemistry and Materials Engineering, Jiangsu Key Laboratory of Advanced Functional Materials, Changshu Insititute of Technology, Changshu, PR ChinaView further author information
,
Wang-Shui CaiSchool of Chemistry and Materials Engineering, Jiangsu Key Laboratory of Advanced Functional Materials, Changshu Insititute of Technology, Changshu, PR ChinaView further author information
,
Xiao-Yan TangSchool of Chemistry and Materials Engineering, Jiangsu Key Laboratory of Advanced Functional Materials, Changshu Insititute of Technology, Changshu, PR ChinaView further author information
&
Rong-Xin YuanSchool of Chemistry and Materials Engineering, Jiangsu Key Laboratory of Advanced Functional Materials, Changshu Insititute of Technology, Changshu, PR ChinaView further author information
Pages 1633-1643 | Received 12 Aug 2013, Accepted 30 Jan 2015, Published online: 16 Mar 2015
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

The reactions of cyclohexenephosphonic acid (C6H9PO3H2) and 3-(2-pyridyl)pyrazole (2-pyPzH) with copper(II) chloride and copper(II) bromide affords a 1-D compound [Cu(2-pyPz)Cl] (1) and a decanuclear [Cu10(OH)4(C6H9PO3)6(2-pyPz)4] (2) cage complex. In 1, adjacent copper ions are bridged by two 2-pyPz ligands into dimers, which are further linked by Cl− into a ladder-like chain. Compound 2 has a decanuclear cage structure, the overall cage can be viewed as composed of two Cu4(OH)2(2-pyPz)2 wings that are bridged by a central Cu2P2O6 rim. Variable-temperature magnetic susceptibility studies indicate that both compounds show antiferromagnetic interactions between copper centers.

Additional information

Funding

This work is supported by NSFC [grant number 21201025]; NSF of Jiangsu Provence [grant number BK2012643], [grant number 12KJA150001], [grant number 14KJA150001], the Six Talent Peaks project in Jiangsu Province.

Log in via your institution

Access through your institution

Log in to Taylor & Francis Online

Restore content access

Restore content access for purchases made as guest
Purchase options * Save for later

PDF download + Online access

  • 48 hours access to article PDF & online version
  • Article PDF can be downloaded
  • Article PDF can be printed
USD 61.00 Add to cart

Issue Purchase

  • 30 days online access to complete issue
  • Article PDFs can be downloaded
  • Article PDFs can be printed
USD 1,057.00 Add to cart

* Local tax will be added as applicable

Related Research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.