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Journal of Coordination Chemistry Volume 68, 2015 - Issue 17-18: Special Issue to Honour Professor Dr. Rudi van Eldik on the occasion of his 70th birthday
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Articles

Transition metal complexes with cage-opened diamondoid tetracyclo[7.3.1.14,12.02,7]tetradeca-6.11-diene

Lars ValentinInstitute of Inorganic and Analytical Chemistry, Justus-Liebig University, Gießen, Germany
,
Anja HenssInstitute of Inorganic and Analytical Chemistry, Justus-Liebig University, Gießen, Germany
,
Boryslav A. TkachenkoInstitute of Organic Chemistry, Justus-Liebig University, Gießen, Germany
,
Andrey FokinDepartment of Organic Chemistry, Kiev Polytechnic Institute, Kiev, Ukraine
,
Peter R. SchreinerInstitute of Organic Chemistry, Justus-Liebig University, Gießen, Germany
,
Sabine BeckerInstitute of Inorganic and Analytical Chemistry, Justus-Liebig University, Gießen, Germany
,
Christian WürteleInstitute of Inorganic and Analytical Chemistry, Justus-Liebig University, Gießen, Germany
&
Siegfried SchindlerInstitute of Inorganic and Analytical Chemistry, Justus-Liebig University, Gießen, GermanyCorrespondence[email protected]
 show all
Pages 3295-3301 | Received 09 Apr 2015, Accepted 22 Jun 2015, Published online: 14 Aug 2015
 
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Abstract

Cage-opened diamondoid tetracyclo[7.3.1.14,12.02,7]tetradeca-6,11-diene forms complexes with AgNO3 and CuCl. The latter crystallized from acetonitrile in polymeric form [Cu2Cl2(CH3CN)(diene)]n; in the presence of 2,2′-bipyridine, a double-charged monomeric Cu(I)-complex [Cu2(bipy)2(diene)]2+ formed. Both complexes were structurally characterized through X-ray crystal diffraction analysis.

Graphical abstract

Copper(I) complexes with the diamantane diene tetracyclo[7.3.1.14,12.02,7]tetradeca-6.11-diene (6) have been prepared and an interesting crystal structure, [Cu2(bipy)2(6)]2+ (hydrogen atoms, anions, and solvent molecules are omitted for clarity), was obtained.

Notes

Dedicated to the 70th birthday of Rudi van Eldik.

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