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Journal of Coordination Chemistry Volume 69, 2016 - Issue 19
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Articles

A Zn(II) luminescent polymer as a multifunctional sensor to nitrobenzene, Fe3+ and CrO42− ions

Jun WangSchool of Chemistry and Environmental Engineering, Sichuan University of Science & Engineering, Zigong, PR China;Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry & Materials Science, Northwest University, Xi’an, PR ChinaCorrespondence[email protected]
,
Lu LuSchool of Chemistry and Environmental Engineering, Sichuan University of Science & Engineering, Zigong, PR China
,
Wei-Ping WuSchool of Chemistry and Environmental Engineering, Sichuan University of Science & Engineering, Zigong, PR China
,
Huai-Ming HuKey Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry & Materials Science, Northwest University, Xi’an, PR China
&
Bin XieSchool of Chemistry and Environmental Engineering, Sichuan University of Science & Engineering, Zigong, PR China
Pages 2872-2880 | Received 26 Apr 2016, Accepted 19 Jul 2016, Published online: 06 Sep 2016
 
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Abstract

A metal-organic framework of {[Zn(tib)2]·2NO3} (tib = 135-tris(1-imidazolyl)benzene) (1) has been synthesized and characterized. The structure determination reveals that 1 is a 2-D layer network and exhibits a classical hxl topology. 1 shows selective properties in the detection of nitrobenzene and Fe3+. Furthermore, 1 also exhibits an excellent capability to detect CrO42−. The present work indicates that 1 could be taken as a potential candidate for developing multifunctional luminescence sensors.

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