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Journal of Coordination Chemistry Volume 69, 2016 - Issue 24
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Articles

Synthesis, characterization and luminescent properties of three-coordinate copper(I) halide complexes containing 2-(diphenylphosphino)biphenyl

Lei QiHubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, School of Chemistry and Chemical Engineering, Hubei University, Wuhan, PR China
,
Qian LiHubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, School of Chemistry and Chemical Engineering, Hubei University, Wuhan, PR China
,
Xiao HongHubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, School of Chemistry and Chemical Engineering, Hubei University, Wuhan, PR China
,
Li LiuHubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, School of Chemistry and Chemical Engineering, Hubei University, Wuhan, PR ChinaCorrespondence[email protected]
,
Xin-Xin ZhongHubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, School of Chemistry and Chemical Engineering, Hubei University, Wuhan, PR China
,
Qiao ChenHubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, School of Chemistry and Chemical Engineering, Hubei University, Wuhan, PR China
,
Fa-Bao LiHubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, School of Chemistry and Chemical Engineering, Hubei University, Wuhan, PR ChinaCorrespondence[email protected]
,
Qian LiuInstitute of Molecular Functional Materials and Department of Chemistry and Partner State Key Laboratory of Environmental and Biological Analysis, Hong Kong Baptist University, Hong Kong, PR China
,
Hai-Mei QinFujian Provincial Key Lab of Theoretical and Computational Chemistry, and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, PR China
&
Wai-Yeung WongInstitute of Molecular Functional Materials and Department of Chemistry and Institute of Advanced Materials, Hong Kong Baptist University, Hong Kong, PR ChinaCorrespondence[email protected]
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Pages 3692-3702 | Received 23 Apr 2016, Accepted 16 Aug 2016, Published online: 04 Oct 2016
 
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Abstract

Highly emissive three-coordinate copper halide complexes with a bidentate phosphine ligand have attracted attention. Here, a series of three-coordinate mono- and dinuclear copper halide complexes, [CuI(dpbp)2] (1) and [CuX(dpbp)]2 (dpbp = 2-(diphenylphosphino)biphenyl, X = Br (2), Cl (3)), were synthesized, and their molecular structures and photophysical properties were investigated. In the solid state, these complexes exhibit green photoluminescence with microsecond lifetimes (λmax = 515–538 nm; τ = 11.8–19.1 μs) at 298 K. The emission of the complexes originates from the (σ + X) → π* transition. All three complexes displayed good thermal stability.

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