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Journal of Coordination Chemistry Volume 70, 2017 - Issue 9
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Short Communication

Coordination modes of 2-mercapto-1,3-benzothiazolate in gallium and indium complexes

Dariusz BasiakFaculty of Chemistry, Warsaw University of Technology, Warsaw, PolandCorrespondence[email protected]
,
Wanda ZiemkowskaFaculty of Chemistry, Warsaw University of Technology, Warsaw, Poland
,
Paweł SochaDepartment of Chemistry, University of Warsaw, Warsaw, Poland
,
Łukasz DobrzyckiDepartment of Chemistry, University of Warsaw, Warsaw, Poland
,
Zbigniew OchalFaculty of Chemistry, Warsaw University of Technology, Warsaw, Poland
&
Edyta PindelskaFaculty of Pharmacy, Department of Inorganic and Analytical Chemistry, Medical University of Warsaw, Warsaw, Poland
Pages 1528-1535 | Received 05 Jan 2017, Accepted 20 Mar 2017, Published online: 12 Apr 2017
 
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Abstract

2-Mercapto-1,3-benzothiazole (mbztH) may act as a chelating or bridging ligand. In this study, reactions of mbztH with Me3Ga and Me3In were examined. The products were characterized by NMR spectroscopy, elemental analyses, melting point, and molecular weight determinations. Formation of mononuclear chelating complexes Me2M(mbzt) (M = Ga, In) was observed in solutions. Crystallization of Me2M(mbzt) yielded uncommon non-symmetrical dinuclear complexes Me4M2(mbzt)2, in which one metal is bonded to two sulfurs and the other to two nitrogens.

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