Advanced search
Publication Cover
Journal of Coordination Chemistry Volume 70, 2017 - Issue 11
Submit an article Journal homepage
122
Views
4
CrossRef citations to date
0
Altmetric
Articles

Synthesis, crystal structure, and photo/electrocatalytic properties of a 1D chain based on monocobalt-substituted arsenotungstates

Chu WuKey Laboratory for Photonic and Electronic Bandgap Materials, Ministry of Education, Harbin Normal University, Harbin, People’s Republic of China;Key Laboratory of Synthesis of Functional Materials and Green Catalysis, Colleges of Heilongjiang Province, Harbin Normal University, Harbin, People’s Republic of China
,
Jinghua LvKey Laboratory for Photonic and Electronic Bandgap Materials, Ministry of Education, Harbin Normal University, Harbin, People’s Republic of China
,
Kai YuKey Laboratory for Photonic and Electronic Bandgap Materials, Ministry of Education, Harbin Normal University, Harbin, People’s Republic of China;Key Laboratory of Synthesis of Functional Materials and Green Catalysis, Colleges of Heilongjiang Province, Harbin Normal University, Harbin, People’s Republic of ChinaCorrespondence[email protected]
,
He ZhangKey Laboratory for Photonic and Electronic Bandgap Materials, Ministry of Education, Harbin Normal University, Harbin, People’s Republic of China;Key Laboratory of Synthesis of Functional Materials and Green Catalysis, Colleges of Heilongjiang Province, Harbin Normal University, Harbin, People’s Republic of China
,
Chunmei WangKey Laboratory for Photonic and Electronic Bandgap Materials, Ministry of Education, Harbin Normal University, Harbin, People’s Republic of China;Key Laboratory of Synthesis of Functional Materials and Green Catalysis, Colleges of Heilongjiang Province, Harbin Normal University, Harbin, People’s Republic of China
,
Chunxiao WangKey Laboratory for Photonic and Electronic Bandgap Materials, Ministry of Education, Harbin Normal University, Harbin, People’s Republic of China;Key Laboratory of Synthesis of Functional Materials and Green Catalysis, Colleges of Heilongjiang Province, Harbin Normal University, Harbin, People’s Republic of China
&
Baibin ZhouKey Laboratory for Photonic and Electronic Bandgap Materials, Ministry of Education, Harbin Normal University, Harbin, People’s Republic of China;Key Laboratory of Synthesis of Functional Materials and Green Catalysis, Colleges of Heilongjiang Province, Harbin Normal University, Harbin, People’s Republic of ChinaCorrespondence[email protected]
 show all
Pages 1862-1871 | Received 15 Feb 2017, Accepted 18 Apr 2017, Published online: 11 May 2017
 
Sample our Engineering & Technology journals, sign in here to start your access, latest two full volumes FREE to you for 14 days

Abstract

A chain based on the Keggin polyoxoanions, (H2bipy)2(Hbipy) [AsW11CoO39]·H2O (bipy = 4,4′-bipyridine) (1) has been hydrothermally synthesized and characterized by elemental analysis, IR, UV, TG, and single-crystal X-ray diffraction. In 1, substituted cobalt atoms share half occupancy sites with two W atoms on two asymmetric positions of opposite W3O13 trimers forming mono-substituted Keggin arsenotungstate. The Keggin clusters of two different arrays are alternately connected to generate unique wave-like chains in –A–B–A–B– ways via Co–O–W bridge. Compound 1 exhibits bifunctional electrocatalytic behavior for oxidation of ascorbic acid (AA) and reduction of hydrogen peroxide (H2O2), and good degradation ability for three typical dyes under UV light.

Log in via your institution

Access through your institution

Log in to Taylor & Francis Online

Restore content access

Restore content access for purchases made as guest
Purchase options * Save for later

PDF download + Online access

  • 48 hours access to article PDF & online version
  • Article PDF can be downloaded
  • Article PDF can be printed
USD 61.00 Add to cart

Issue Purchase

  • 30 days online access to complete issue
  • Article PDFs can be downloaded
  • Article PDFs can be printed
USD 1,057.00 Add to cart

* Local tax will be added as applicable

Related Research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.