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Journal of Coordination Chemistry Volume 71, 2018 - Issue 1
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Synthesis, crystal structure, and properties of a tetrairon cluster based on 2-methyl-8-hydroxyquinoline

Ting MengState Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources, School of Chemistry & Pharmacy of Guangxi Normal University, Guilin, P. R. China
,
Jia-Shun WangState Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources, School of Chemistry & Pharmacy of Guangxi Normal University, Guilin, P. R. China
,
Hua-Hong ZouState Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources, School of Chemistry & Pharmacy of Guangxi Normal University, Guilin, P. R. ChinaCorrespondence[email protected]
,
Feng-Hua LiangState Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources, School of Chemistry & Pharmacy of Guangxi Normal University, Guilin, P. R. China
&
Fu-Pei LiangState Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources, School of Chemistry & Pharmacy of Guangxi Normal University, Guilin, P. R. China;Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin, P. R. ChinaCorrespondence[email protected]
Pages 57-67 | Received 21 Oct 2017, Accepted 12 Jan 2018, Published online: 09 Feb 2018
 
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Abstract

The synthesis, structure, and magnetic properties of a tetrairon(III) complex [Fe4(μ2-O)2Cl4(L)4]·0.5H2O (1, L = 2-methyl-8-hydroxyquinoline), which was prepared under solvothermal conditions and characterized by IR spectra, elemental analysis, TG, and single-crystal X-ray crystal diffraction, are presented. Each Fe center adopts a distorted trigonal bipyramid geometry and is coordinated with three oxygen atoms, one nitrogen atom, and one chlorine atom. Each 2-methyl-8-hydroxyquinoline is coordinated to two FeIII ions with μ2-η2:η1 coordination mode. The magnetic properties of the complex are dominated by antiferromagnetic exchange interactions.

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