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Journal of Coordination Chemistry Volume 73, 2020 - Issue 5
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Articles

Two pentanuclear clusters: synthesis, crystal structures, luminescent and magnetic properties

Ying-Ying WangKey Laboratory of Inorganic Chemistry in Universities of Shandong, Department of Chemistry and Chemical Engineering, Jining University, Qufu, ChinaView further author information
,
Ran LiuKey Laboratory of Inorganic Chemistry in Universities of Shandong, Department of Chemistry and Chemical Engineering, Jining University, Qufu, ChinaView further author information
,
Yang-Yang GuoKey Laboratory of Inorganic Chemistry in Universities of Shandong, Department of Chemistry and Chemical Engineering, Jining University, Qufu, ChinaView further author information
,
Han WangKey Laboratory of Inorganic Chemistry in Universities of Shandong, Department of Chemistry and Chemical Engineering, Jining University, Qufu, ChinaView further author information
,
Jing-Quan ShaKey Laboratory of Inorganic Chemistry in Universities of Shandong, Department of Chemistry and Chemical Engineering, Jining University, Qufu, ChinaView further author information
&
Hai-Feng ZhangKey Laboratory of Inorganic Chemistry in Universities of Shandong, Department of Chemistry and Chemical Engineering, Jining University, Qufu, ChinaCorrespondence[email protected]
View further author information
Pages 813-822 | Received 02 Oct 2019, Accepted 12 Mar 2020, Published online: 23 Apr 2020
 
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Abstract

Reactions of N,2-dihydroxy-3-methoxybenzamide (H3L) with transition metal acetates in the presence of pyridine and/or 2,2′-bipyridine under solvothermal conditions give two pentanuclear complexes, [Zn5L2(CH3COO−)4(py)3] (1) and [Co5L2(CH3COO−)4(py)(2,2′-bipy)2] (2). Photoluminescence studies indicate strong purple emission for 1 in the solid state at room temperature. Variable-temperature dc magnetic susceptibility studies of 2 reveal that antiferromagnetic CoII···CoII exchange interactions exist in 2.

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Disclosure statement

No potential conflict of interest was reported by the author(s).

Additional information

Funding

We gratefully acknowledge the financial support from the National Science Foundation of China (Grant No: 21771061), A Project of Shandong Province Higher Educational Science and Technology Program (J12LD54), the Youths Science Foundation of Jining University (No. 2017BSZX09) and Talent Culturing Plan for Leading Disciplines of University in Shandong Province.

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