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Journal of Coordination Chemistry Volume 74, 2021 - Issue 4-6
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Research Article

Characterization, luminescent and magnetic analysis of five new lanthanide complexes based on carboxylate ligands

Fei Xiea Key Laboratory of Energy Materials Chemistry, Ministry of Education; Key Laboratory of Advanced Functional Materials, Autonomous Region; Institute of Applied Chemistry, College of Chemistry, Xinjiang University, Urumqi, Xinjiang, P. R. ChinaView further author information
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Lu-Lu Wanga Key Laboratory of Energy Materials Chemistry, Ministry of Education; Key Laboratory of Advanced Functional Materials, Autonomous Region; Institute of Applied Chemistry, College of Chemistry, Xinjiang University, Urumqi, Xinjiang, P. R. ChinaView further author information
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Ru-Xia Yanga Key Laboratory of Energy Materials Chemistry, Ministry of Education; Key Laboratory of Advanced Functional Materials, Autonomous Region; Institute of Applied Chemistry, College of Chemistry, Xinjiang University, Urumqi, Xinjiang, P. R. ChinaView further author information
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Yu-Ming Yua Key Laboratory of Energy Materials Chemistry, Ministry of Education; Key Laboratory of Advanced Functional Materials, Autonomous Region; Institute of Applied Chemistry, College of Chemistry, Xinjiang University, Urumqi, Xinjiang, P. R. ChinaView further author information
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Duo-Zhi Wanga Key Laboratory of Energy Materials Chemistry, Ministry of Education; Key Laboratory of Advanced Functional Materials, Autonomous Region; Institute of Applied Chemistry, College of Chemistry, Xinjiang University, Urumqi, Xinjiang, P. R. ChinaCorrespondence[email protected] [email protected]
ORCID Iconhttps://orcid.org/0000-0001-7386-625XView further author information
ORCID Icon &
Ya-Xin Zhangb School of Chemical Engineering and Technology, Xinjiang University, Urumqi, P. R. ChinaView further author information
Pages 598-615 | Received 10 Jan 2020, Accepted 12 Dec 2020, Published online: 04 Mar 2021
 
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Abstract

Five new lanthanide complexes, [Pr(HL1)(H2O)4]Cl2·2H2O (1), [Ho(HL1) (H2O)3]Cl2·2H2O (2), [Dy(HL1)(H2O)3]Cl2·2H2O (3), [Dy(H2L2)2(H2O)6]Cl3 (4) and [Ce(H2L3)(CH3CO2)2(H2O)2]·H2O (5), based on carboxylate ligands have been prepared. All complexes have been characterized via elemental analysis, single-crystal X-ray diffraction, powder X-ray diffraction and thermogravimetric analysis. According to single-crystal X-ray analysis, 1–3 and 5 are coordination polymers (CPs) with 1D zigzag chains, while 4 is a 0D structure. The 3D supramolecular structures of 1–4 are formed by the interaction of C/N − H···Cl hydrogen bonds and π···π stacking interactions. In addition, the luminescent and magnetic properties of 1–5 have been discussed.

Graphical Abstract

Disclosure statement

No potential conflict of interest was reported by the authors.

Additional information

Funding

This work was financially supported by the Natural Science Funds of Xinjiang, China [No. 2019D01C042].

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