Abstract
A UiO-67-type Zr-based metal–organic framework (MOF) with dibenzothiophene linkers, UiO-67-S, was synthesized using a solvothermal method. The crystal structure of UiO-67-S exhibits the same topological structure as UiO-67 and its derivatives. UiO-67-S shows high thermal stability and excellent permanent porosity. Moreover, its excellent hydrogen storage indicates that the thiophene moiety is suitable for enhancing the hydrogen storage ability of MOFs.
Disclosure statement
The authors declare no conflict of interest.