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Phase Transitions
A Multinational Journal
Volume 86, 2013 - Issue 6
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Original Articles

Ternary compounds and isothermal section in Lu–Fe–Ga ternary system at 773 K

, , , , &
Pages 585-597 | Received 25 Apr 2012, Accepted 28 May 2012, Published online: 26 Jun 2012
 

Abstract

The isothermal section of the Lu–Fe–Ga ternary system at 773 K was investigated and constructed based on X-ray powder diffraction analysis. Thirteen binary compounds, Lu2Fe17, Lu6Fe23, LuFe2, LuGa3, LuGa2, Lu3Ga5, LuGa, Lu3Ga2, Lu5Ga3, Fe3Ga, Fe6Ga5, Fe3Ga4, FeGa3, nine ternary solid solutions, T1-LuFe2–1.43Ga0–0.57, T2-LuFe1.34–0.92Ga0.68–1.08, T3-LuFe0.52–0.26Ga1.48–1.74, T5-LuFe2.04–1.72Ga0.96–1.28, T6-Lu6Fe23–21.4Ga0–1.6, T7-Lu2Fe17–14.5Ga0–3.5, T8-Lu2Fe12.9–8.1Ga4.1–8.9, T9-LuFe6.8–5.5Ga5.2–6.5, T10-LuFe5.2–4.5Ga6.8–7.5, and two ternary compounds, T4-LuFe2.35Ga0.65 and T11-Lu2FeGa8 have been confirmed. The structures of the five new ternary compounds or solid solution T2, T3, T4, T5 and T8 are determined by Rietveld refinement method.

Acknowledgements

The work was supported by the National Natural Science Foundation of China (Grant Nos. 50871070, 51171117, and 51101103) and Shenzhen Science and Technology Research (Grant No. JC200903120081A).

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