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Phase Transitions
A Multinational Journal
Volume 87, 2014 - Issue 4
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Original Articles

Effect of Al particle size on the reaction kinetics and densification of TiAl intermetallics

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Pages 344-356 | Received 03 May 2013, Accepted 27 Jun 2013, Published online: 15 Aug 2013
 

Abstract

The present investigation deals with response of the particle size of aluminum on the reactive sintering of Ti–Al intermetallics and subsequently on their reaction kinetics and densification behavior. Aluminum powders of initial average particle size of 44 μm were milled for various durations in a planetary ball mill to produce average particles sizes of 100, 28 and 7 μm. These aluminum powders of various particle sizes i.e. 100, 28 and 7 μm were mixed with titanium powder of average particles size of 44 μm in the ratio of 1:1 corresponding to the Ti–Al intermetallic composition. The reactive sintering temperatures of the mixtures were determined by DTA and the effect of change in particle Al particle size has been determined for the activation energy ofthe self-propagating reaction. The effect of Al particle size on the sintering was determined by studying density and microstructure.

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