Dielectric relaxation and ac conduction in multiferroic Bi_0.8Gd_0.1Pb_0.1Fe_0.9Ti_0.1O₃ ceramics: impedance spectroscopy analysis

ABSTRACT

The solid solutions of Bi_0.8Gd_0.1Pb_0.1Fe_0.9Ti_0.1O₃ have been prepared by the solid-state reaction method. The preliminary structural studies were carried out by X-ray diffraction technique showing the formation of polycrystalline sample with ABO₃ type of perovskite structure with hexagonal symmetry for the Bi_0.8Gd_0.1Pb_0.1Fe_0.9Ti_0.1O₃ ceramic system at room temperature. Dielectric properties and impedance study of this ceramic have been characterized in the temperature range room temperature to 375 °C and frequency range 100 Hz–1 MHz. The maximum ferroelectric transition temperature (T_c) of this system was in the range 200 °C–260 °C with the dielectric constant of peak to be ∼30,170 at 1 kHz. The complex impedance plot exhibited one impedance semicircle observed at low temperature, whereas two semicircles above 80 °C and the centres of the semicircles lie below the real axis, which indicates that the material is non-Debye type. Single semicircle is explained by the grain effect of the bulk and double semicircle is due to the bulk and grain boundary effect. The bulk resistance and grain boundary resistance of the materials decrease with the increasing temperature, showing negative temperature and a typical semiconducting property, i.e. negative temperature coefficient of resistance behaviour.

KEYWORDS:

• X-ray diffraction
• dielectric properties
• electrical properties
• lattice Strain
• impedance spectroscopy

Disclosure statement

No potential conflict of interest was reported by the authors.

Additional information

Funding

Authors are grateful to the Defence Research and Development Organization (DRDO), Govt. of India, for financial support under the research project ERIP/ER/1303129/M/01/1564.