Influence on the phase transitions of barium titanate of the manganese valency, introduced as a substituant in the titanium site

E. Duverger Laboratoire de Physique des Solides, URA CNRS 785, Universiteé de Bourgogne, F-21004, Dijon Cedex, France

B. Jannot Laboratoire de Physique des Solides, URA CNRS 785, Universiteé de Bourgogne, F-21004, Dijon Cedex, France

M. Maglione Laboratoire de Physique des Solides, URA CNRS 785, Universiteé de Bourgogne, F-21004, Dijon Cedex, France

J. C. Jules Laboratoire de Réactivité des Solides, URA CNRS 23, Université de Bourgogne, F-21004, Dijon Cedex, France

J. C. Niepce Laboratoire de Réactivité des Solides, URA CNRS 23, Université de Bourgogne, F-21004, Dijon Cedex, France

Abstract

A small amount of manganese introduced in BaTiO₃ modifies strongly the vibrational and electronic properties of the pure compound. Dielectric response and EPR measurements are reported in order to study the influence of the manganese valency on the ferroelectric-paraelectric phase transition.

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Influence on the phase transitions of barium titanate of the manganese valency, introduced as a substituant in the titanium site

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Influence on the phase transitions of barium titanate of the manganese valency, introduced as a substituant in the titanium site

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