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Original Articles

Tunnelling of heavy particles in the low temperature chemistry

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Pages 1-70 | Published online: 11 Aug 2008
 

Abstract

The quantum dynamics of cryochemical solid-state reactions in the region of the low-temperature limit for the rate constant is considered in the framework of multidimensional nuclear tunnelling when low-frequency displacements of heavy particles lead to the formation of reaction complexes with high barrier transparency.

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