Arsenic Removal Behavior by Fe-Al Binary Oxide: Thermodynamic and Kinetic Study

Abstract

In this study, thermodynamic and kinetic behaviors of As(V) and As(III) adsorption on Fe-Al binary oxide were investigated. Adsorptions of both As(V) and As(III) on Fe-Al binary oxide were exothermic reactions (ΔH⁰ < 0) and occurred spontaneously (ΔG⁰ < 0). Because of strong electrostatic interaction between the As(V) anion and the positive Fe-Al binary oxide, As(V) was adsorbed rapidly and the adsorption rate was controlled by chemical adsorption. On the other hand, As(III) exists in a nonionic form, because of which it was not adsorbed through strong attractive forces. Therefore, the adsorption rate of As(III) was controlled by a combination of diffusion processes and chemical sorption.

Keywords:

• activation energy
• arsenic
• Fe-Al binary oxide
• kinetic
• thermodynamic

ACKNOWLEDGEMENTS

This work was supported by the Advanced Biomass R&D Center (ABC) of Korea Grant funded by the Ministry of Education, Science and Technology (ABC-2010-0029728) and by a grant (C106A1520001-06A085500134) from Plant Technology Advancement Program funded by Ministry of Construction and Transportation of the Korean government.