Removal of Reactive Turquoise Blue Dye from Aqueous Solution Using a Non-Conventional Natural Adsorbent

Abstract

Batch and fixed bed experiments were carried out for the removal of Reactive Turquoise Blue Q-G125% (TB) dye from aqueous solution using cashew apple bagasse (CAB) as non-conventional adsorbent. CAB, a lignocellulosic material, used in this study contained 20.56% ± 2.19% cellulose, 10.17% ± 0.89% hemicellulose, and 35.26% ± 0.90% lignin and was characterized as nonporous material and its surface area cannot be determined by nitrogen adsorption at 77 K. Kinetic and equilibrium study were performed in batch systems, evaluating the effects of pH, contact time, initial concentration, adsorbent loading, and temperature on the adsorption. The pseudo-second-order model best described the adsorption kinetic data. The adsorption isotherms of TB onto CAB were well fitted by the Freundlich model. The maximum adsorption capacity of the biomass was 145.10 mg/g and high levels of dye removal (> 90%) at 60°C. According to thermodynamic results, the adsorption of TB onto CAB is a spontaneous endothermic process. Dynamic adsorption behavior was studied in fixed bed system. The highest bed adsorbed quantity of 32 mg/g with 100 mg/L TB initial concentration at 1 mL/min flow rate and 1.4 cm bed-height was obtained. The results showed that CAB is a promising adsorbent for the adsorption of the dye.

Keywords:

• cashew apple bagasse
• bioadsorbent
• reactive dye
• batch adsorption
• fixed bed adsorption