EXTRACTORS FOR ESTIMATING PLANT AVAILABLE SILICON FROM POTENTIAL SILICON FERTILIZER SOURCES

Abstract

Methods to quantify plant available silicon (Si) from Si-based slags for use as fertilizers are not well defined. Although it is possible to estimate total Si from a potential Si fertilizer source; this approach does not represent how much Si is available for uptake by the plant. In this study, Si was extracted from ten sources [Wollastonite W10; calcium silicate slag from the US; calcium silicate from Canada; magnesium silicate; Excellerator; silican gel; 00-00-12 + Si (liquid source) and three types of potassium silicate with different concentrations in the liquid form, K53; K120 and AgSil^TM25] using each of the following seven methods: hydrochloric acid (HCl) plus hydrofluoric acid (HF) extraction, leaching column; sodium carbonate (Na₂CO₃–10 g L⁻¹) + ammonium nitrate (NH₄NO₃–16 g L⁻¹); citric acid (50 g dm⁻³ or 5%); hydrochloric acid (0.5 N); neutral ammonium citrate (NAC); and resin (Amberlite IRC-50, pK 6.1). All the Si-containing products were added to pots at rates equal to 600 kg ha⁻¹ of Si based on the total Si extracted. Poa trivialis cv. ‘Darkhorse’ was grown for 24 days with these sources to determine Si plant uptake. Based on the correlation coefficients, the best extractor for available Si in solid fertilizer was determined to be Na₂CO₃ + NH₄NO₃, while for liquid fertilizers, the total Si (HCl + HF) was found to be the best. Consequently, regulatory agencies now have two extractors for estimating the plant available Si from fertilizers depending on the physical property of the material (solid or liquid).

Keywords:

• general plant nutrition
• analytical procedures
• fertilizers

Notes

*Based on molecular weight.

**As provided by companies, NP = not provided.

*Liquid fertilizers.