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Ozone: Science & Engineering
The Journal of the International Ozone Association
Volume 27, 2005 - Issue 1
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Original Articles

The Evaluation Of Ozonation and Chlorination On Disinfection By-Product Formation for a High-Bromide Water

, , , &
Pages 19-26 | Published online: 18 Jan 2007
 

Abstract

High-bromide raw water was ozonated or chlorinated with and without hydrogen peroxide to study the effect of the disinfectants on the disinfection by-product (DBP) formation. Less bromate was formed when ozonation was made at the ambient pH of 5.8 as compared to ozonation at pH 7, showing the effectiveness of pH reduction in controlling the bromate formation. When chlorine dose was 1 mg/L instead of 2.3 mg/L, the trihalomethane formation was 50 μg/L instead of >100 μg/L, and the proportional distribution of the trihalomethanes was similar. The use of ozone for this water could provide good results in respect of the DBP formation.

Acknowledgments

This study was funded by the Academy of Finland and the Technology Development Centre of Finland (project no. 34538). Special thanks to Ms. Miia Hämäläinen, Mrs. Teija Korhonen, and Mrs. Mervi Ojala from the Laboratory of Chemistry of the National Public Health Institute, and Mr. Matti Pessi from the University of Kuopio for technical assistance.

Notes

10. EU, “Official Journal of the European Community L330: Directive 98/83/EC,” (1998).

Finnish Standards Association SFS. SFS 3005. “Determination of Alkalinity and Acidity in Water. Potentiometric Titration,” Finnish Standards Association SFS, Helsinki, Finland (1981).

13. Finnish Standards Association SFS. SFS-EN 1484. “Water Analysis. Guidelines for the Determination of Total Organic Carbon (TOC) and Dissolved Organic Carbon (DOC),” Finnish Standards Association SFS, Helsinki, Finland (1997).

19. ISO/DIS 10301. “Water Quality– Determination of Highly Volatile Halogenated Hydrocarbons — Gas-Chromatographic Methods,” International Organization for Standardization (ISO) (1994).

35. USEPA. Stage 1 Disinfectants and Disinfection By-Products Rule. Unites States Environmental Protection Agency, EPA 815-F-98-010, (1998).

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