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Ozone: Science & Engineering
The Journal of the International Ozone Association
Volume 35, 2013 - Issue 2
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Original Articles

The Advanced Oxidation Process of Phenol Solution by O3/H2O2 in a Rotating Packed Bed

Ze-Quan Zeng State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing, 100029, PR China
,
Jun-Fang Wang State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing, 100029, PR China
,
Zhen-Hao Li Petrochemical Research Institute, China National Petroleum Corporation, Beijing, 100195, PR China
,
Bao-Chang Sun State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing, 100029, PR China
,
Lei Shao State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing, 100029, PR China
,
Wen-Jun Li State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing, 100029, PR China
,
Jian-Feng Chen State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing, 100029, PR China
&
Hai-Kui Zou State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing, 100029, PR ChinaCorrespondence[email protected]
 show all
Pages 101-108 | Received 31 Oct 2011, Accepted 27 Jul 2012, Published online: 27 Mar 2013
 
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Abstract

This article presents experimental investigation on the oxidative treatment of phenol in water by O3/H2O2 in a rotating packed bed (RPB). It was found that the phenol degradation ratio increased with increasing rotation speed, initial pH value of phenol solution, and temperature. The degradation ratio of phenol had a peak value with increasing H2O2 concentration. The optimum operating conditions in this study were determined as an H2O2 concentration of 6.5 mM and a rotation speed of 1200 rpm. Phenol degradation ratio reached 100% at an initial phenol concentration of 40 mg/L in the O3/H2O2 process.

ACKNOWLEDGMENT

This work was supported by National Natural Science Foundation of China (Nos. 20676006, 20990221), National High-Tech Research Program of China (863 Program) (No. 2009AA033301) and Program for New Century Excellent Talents in University of China (NCET-07-0053).

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