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Ozone: Science & Engineering
The Journal of the International Ozone Association
Volume 39, 2017 - Issue 2
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Original Articles

Ozone Solubility in Aqueous Solutions of NaCl, Na2SO4, and K2SO4: Application of the Weisenberger-Schumpe Model for Description of Regularities and Calculation of the Ozone Molar Absorption Coefficient

Boris G. ErshovA. N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences, Moscow119071, RussiaCorrespondence[email protected]
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,
Andrey V. GordeevA. N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences, Moscow119071, RussiaView further author information
&
Aleksandr F. SeliverstovA. N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences, Moscow119071, RussiaView further author information
Pages 69-79 | Received 23 Mar 2016, Accepted 14 Nov 2016, Published online: 17 Jan 2017
 
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ABSTRACT

The ozone solubility in aqueous solutions of salts, NaCl (up to 5 М) and Na2SO4 (up to 2 М) and their mixtures, was studied. The results are adequately described by the semi-empirical model proposed by Weisenberger and Schumpe for calculation of the solubilities of atmospheric gases in concentrated solutions of electrolytes. By comparing the data obtained experimentally and calculated in terms of the Weisenberger and Schumpe model, the ozone molar absorption coefficient was found to be ε = 2860 ± 200 M−1 cm−1 at 260 nm.

Funding

This work was supported by the Russian Foundation for Basic Research under grant number 16-03-00336 A.

Additional information

Funding

This work was supported by the Russian Foundation for Basic Research under grant number 16-03-00336 A.

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