Fate of Cr(III) during Ozonation of Secondary Municipal Wastewater Effluent

ABSTRACT

In the present study, the fate of trivalent chromium (Cr(III)) during ozonation of ultrapurified water and wastewater effluent was investigated. In experiments conducted in phosphate buffered ultrapurified water, O₃ alone in excess was inefficient to oxidize Cr(III) (only about 10–15% of total Cr(III) content), while in presence of the secondary oxidant, OH radical, almost all Cr(III) was oxidized to hexavalent chromium (Cr(VI)). In a wastewater effluent, spiked with Cr(III), only about 10–20% of Cr(III) was oxidized with specific ozone doses in the range 0.15–1.5 gO₃/gDOC, although O₃ and OH radical were both available for reaction. Cr(VI) formation was monitored in parallel with the abatement of some common micropollutants, reacting with differing apparent second-order rate constants with ozone, decreasing in the order carbamazepine>> benzotriazole> atrazine> p-chlorobenzoic acid (pCBA). Carbamazepine and benzotriazole were abated to >80% for specific O₃ doses of 0.3 gO₃/gDOC and 0.8 gO₃/gDOC, respectively. The more ozone-resistant compounds (atrazine and pCBA) required a specific ozone dose of about 1.25 gO₃/gDOC for the same relative abatement. At this specific ozone dose (i.e., 1.25 gO₃/gDOC), only about 20% of Cr(III) was oxidized to Cr(VI), whereas only 10% of Cr(III) was oxidized to Cr(VI) at a more realistic specific ozone dose for enhanced wastewater treatment for micropollutant abatement (0.5 gO₃/gDOC). Therefore, for typical Cr(III) levels in municipal wastewaters, effluent ozonation only leads to toxicologically insignificant Cr(VI) concentrations.

KEYWORDS:

• Chromate
• Cr(Iii)
• Cr(Vi)
• Hydroxyl Radical
• Micropollutants
• Ozonation

Acknowledgments

The authors are thankful to the Swiss National Science Foundation for providing Prof. Katsoyiannis with a short research scholarship, under which he visited EPFL and conducted this research project. Thanks are extended to Professor G. Gallios, Aristotle University of Thessaloniki, for providing speciation calculations based on the Visual Minteq version 3.1 software program.

Disclosure statement

No potential conflict of interest was reported by the authors.

Additional information

Funding

This work was supported by the Swiss National Science Foundation.