An Optimization Study of Cobalt Supported on Activated Carbon for the Catalytic Ozonation of Oxalic Acid: Effect of Operating Parameters and Synergetic Combination

ABSTRACT

In this study, new heterogeneous cobalt (Co) catalysts supported on activated carbon (Co/AC) were developed using a wetness impregnation process. The effect of preparation conditions on catalyst characteristics was examined. This work focused on two key parameters: the impregnation rate and the calcination atmosphere (temperature and time). Different catalysts were prepared by varying the Co loading on AC. Various catalysts were characterized by means of nitrogen sorptiometry at 77K, Boehm and pHpzc analysis. It was found that the catalyst properties and the functional surface groups were affected by the operating conditions. The best surface area was 997.5 m2/g obtained when the activated carbon was impregnated with 5% Co loading and calcined at 350°C for 2 h. The effects of parameters, such as cobalt loading, pH, catalyst dose, and ozone dose, were explored on oxalic acid removal (OA). Results show that the use of Co/AC for heterogeneous catalytic ozonation enhanced the degradation efficiency of oxalic acid (OA) significantly compared with simple ozonation and O3/AC. The main results indicate that the optimum catalytic activity was observed when 5% (wt/wt) of Co was supported on AC reaching a catalytic ozonation efficiency of 95%. The results of total organic carbon removal of 91% were achieved at optimum conditions.

KEYWORDS:

• Ozone
• cobalt catalyst
• catalytic ozonation
• activated carbon
• coupling process